THE CONCEPT OF MULTI-LEVEL MODIFICATION IN THE TECHNOLOGY OF HIGHLY FILLED FLUOROCOMPOSITES

Authors

  • S. Avdeychik Molder LLC
  • A. Antonov Yanka Kupala State University of Grodno
  • A. Lesun Yanka Kupala State University of Grodno

DOI:

https://doi.org/10.31618/ESSA.2782-1994.2021.2.75.154

Keywords:

: polytetrafluoroethylene, nanocomposite, modifier, energetic activity, interfacial interaction, energy and technological compliance

Abstract

The structural and technological aspects of obtaining composite materials based on polytetrafluoroethylene are considered. It is shown that due to the existence of inert components in the process of interfacial interaction with the degree of filling in the traditional technological paradigm implemented, structural paradox manifests itself in proportion to the reduction of the parameter of tensile strength with increasing degree of filling. According to the concept of multi-level modification, the technological principles are proposed to eliminate the negative impact of the structural paradox fluorine composites by controlling the structure of the organization at various levels – molecular, supramolecular, and interfacial phase. Efficient methods of manufacture of products from highly filled fluorine composites containing 25–35 wt. % carbon fiber with parameters of deformation and strength characteristics higher than the corresponding parameters of analogs.

Author Biographies

S. Avdeychik , Molder LLC

PhD in engineering, associate professor, Leading Engineer

A. Antonov , Yanka Kupala State University of Grodno

PhD in engineering, associate professor, associate professor of the department of material science and resource-saving technologies

A. Lesun , Yanka Kupala State University of Grodno

PhD student

References

Ohlopkova A. A., Andrijanova O. A., Popov S. N. Modifikacija polimerov ul'tradispersnymi soedinenijami. – Jakutsk: Izdvo SO RAN, 2003. – 224 s.

Mashkov Ju. K., Ovchar Z. N., Bajbarackaja M. Ju. i dr. Polimernye kompozicionnye materialy v tribotehnike. – M.: Nedra-Biznescentr, 2004. – 262 s.

Sirenko G. A. Antifrikcionnye karboplastiki. – Kiev: Tehnika, 1985. – 195 s.

Ohlopkova A. A., Petrova P. N., Gogoleva O. V. Razrabotka polimernyh nanokompozitov tribotehnicheskogo naznachenija // Perspektivnye materialy. – 2008. – № 6, Ch. 2. – S. 213–217.

Ginzburg B. M., Tochil'nikov D. T. Vlijanie fullerensoderzhashhih dobavok k ftoroplastam na ih nesushhuju sposobnost' pri trenii // Zhurnal tehnicheskoj fiziki. – 2001. – T. 71, vyp. 2. – S. 120–124. 6. Voropaev V.V., Avdejchik S.V., Struk V.A. Tehnologija formirovanija vysokoprochnyh iznosostojkih ftorkompozitov / Vesci NAN Belarusi: ser. fiz.-tjehn. navuk, 2014, № 1. – S. 51–59.

Avdejchik S. V., Zaharov Ju. N., Ishhenko M. V. i dr. Ftorsoderzhashhie ingibitory iznashivanija metallopolimernyh sistem. – Minsk: Tjehnalogіja, 2011. – 270 s.

Shelestova V. A. Konstrukcionnye materialy tribotehnicheskogo naznachenija na osnove modificirovannyh uglevolokon i politetraftorjetilena: avtoref. dis. … kand. tehn. nauk: 05.02.01. – Gomel': IMMS NAN Belarusi, 2002. – 22 s.

Ignat'eva L.N., Mashhenko V.A., Shaulov A. i dr. Kompozitnye materialy na osnove ftoroplasta F-4MB i nizkoplavkogo oksiftoridnogo stekla // Rossijskij zhurnal fizicheskoj himii A, 2019. – T. 93, S.1652–1656.

Baronin G.S., Buznik V.M., Yurkov G.Yu., et al. Study of Structure and Properties of Polymer Composites Based on Polytetrafluoroethylene and Cobalt Nanoparticles // Inorganic Materials: Applied Research, 2015, Vol. 6, No. 2, pp. 179–186.

Mikhalchan A.A. Lysenko V.A., Salnikova P.Yu. Carbon-fluoropolymer composites: increased electrical conductivity // Fibre Chemistry, 2012, Vol. 44, No 1, p. 46–49.

Berlin A.A. Principy sozdanija kompozicionnyh materialov. – M.: Himija, 1990. –240 s.

Vasil'ev A.P., Ohlopkova A.A., Struchkova T.S. i dr. Razrabotka antifrikcionnyh materialov na osnove politetraftorjetilena s uglerodnymi voloknami // Vestnik SVFU, 2017, №3 (59), s. 39-47.

Mashkov Ju.K., Kurguzova O.A., Ruban A.S. Razrabotka i issledovanie iznosostojkih polimernyh nanokompozitov // Vestnik SibADI, 2018. – Tom 15, № 1 (59), s. 36-45.

Markova M.A., Gotovceva M.E. Issledovanie kompozitov na osnove PTFJe i uglerodnyh napolnitelej // Vestnik nauki i obrazovanija Severo-Zapada Rossii, 2017, t. 3, № 1, S. 1–6.

Pugachev A. K., Rosljakov O. A. Pererabotka ftorplastov v izdelija: tehnologija i oborudovanie. – L.: Himija, 1987. – 168 s.

Avdejchik S. V., Liopo V. A., Ryskulov A. A. i dr. Vvedenie v fiziku nanokompozicionnyh mashinostroitel'nyh materialov / pod nauch. red. V.A. Liopo, V.A. Struka. – Grodno : GGAU, 2009. – 439 s.

Ohlopkova A. A., Vinogradov A. V., Pinchuk L. S. Plastiki, napolnennye ul'tradispersnymi neorganicheskimi soedinenijami. – Gomel': IMMS NAN Belarusi, 1999. – 164 s.

Published

2021-12-16

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Section

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